Influence of phenylphosphonate based flame retardant on epoxy/glass fiber reinforced composites (GRE): Flammability, mechanical and thermal stability properties

Zhao, Xiaomin; Yang, Lingwei; Hueto Martín, Francisco; Zhang, Xiu-Qin; Wang, Rui y Wang, De-Yi (2017). Influence of phenylphosphonate based flame retardant on epoxy/glass fiber reinforced composites (GRE): Flammability, mechanical and thermal stability properties. "Composites Part B: Engineering", v. 110 ; pp. 511-519. ISSN 1359-8368. https://doi.org/10.1016/j.compositesb.2016.10.090.

Descripción

Título: Influence of phenylphosphonate based flame retardant on epoxy/glass fiber reinforced composites (GRE): Flammability, mechanical and thermal stability properties
Autor/es:
  • Zhao, Xiaomin
  • Yang, Lingwei
  • Hueto Martín, Francisco
  • Zhang, Xiu-Qin
  • Wang, Rui
  • Wang, De-Yi
Tipo de Documento: Artículo
Título de Revista/Publicación: Composites Part B: Engineering
Fecha: 1 Febrero 2017
Volumen: 110
Materias:
Palabras Clave Informales: Polymer matrix,,Epoxy reinforced composites, Flammability Fire retardation, Nanoindentation
Escuela: E.T.S.I. Industriales (UPM)
Departamento: Otro
Licencias Creative Commons: Reconocimiento - Sin obra derivada - No comercial

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Resumen

In this work, flame-retardant glass fiber reinforced epoxy composites (FGRE) were successfully prepared via adding a novel phenylphosphonate-based flame retardant, N, N'-diamyl-p-phenylphosphonicdiamide (P-MA) into GRE. FGRE12 showed high LOI value of 33%. Meanwhile, FGRE12 passed V-0 rating in UL 94 test and the peak of heating release rate (pHRR) decreased by 54% in comparison with that of GRE. The flame-retardant efficiency of P-MA in GRE was compared with that in epoxy matrix (EP). Moreover, the influences of P-MA on mechanical and thermal stability properties of GRE were studied systemically. Dynamic mechanical analysis (DMA) studied the influence of P-MA on viscoelasticity of GRE. Fiber push-in test and three-point-bending test were used to evaluate the influence of P-MA on the EP matrix/fiber interface strength and interlamilnar shear strength, respectively. In addition, nanoindentation test was used to study the hardness and Young's modulus of EP matrix. The above results showed that the addition of P-MA did not affect the hardness of epoxy matrix and interfacial strength (epoxy matrix/glass fiber). The influence of P-MA on thermal stability of GRE was studied by thermalgravimetric analysis (TGA). These results would be very important in designing new generation multifunctional epoxy-based composite materials.

Proyectos asociados

TipoCódigoAcrónimoResponsableTítulo
Gobierno de EspañaRYC-2012-10737Sin especificarSin especificarSin especificar
Sin especificarCM1302Sin especificarSin especificarSin especificar

Más información

ID de Registro: 44541
Identificador DC: http://oa.upm.es/44541/
Identificador OAI: oai:oa.upm.es:44541
Identificador DOI: 10.1016/j.compositesb.2016.10.090
URL Oficial: http://www.sciencedirect.com/science/article/pii/S1359836816315803
Depositado por: Memoria Investigacion
Depositado el: 02 Feb 2017 16:12
Ultima Modificación: 02 Feb 2017 16:12
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