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Gordillo Garcia, Nuria ORCID: https://orcid.org/0000-0003-2335-738X, Gonzalez Arrabal, Raquel
ORCID: https://orcid.org/0000-0002-4955-1925, Díaz Chao, Pablo, Ares Fernández, José Ramón, Jiménez Ferrer, Isabel, Ynduráin Muñoz, Félix and Agullo Lopez, Fernando
(2013).
Electronic structure of copper nitrides as a function of nitrogen content.
"Thin Solid Films", v. 531
;
pp. 588-591.
ISSN 0040-6090.
https://doi.org/10.1016/j.tsf.2013.01.030.
Title: | Electronic structure of copper nitrides as a function of nitrogen content |
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Author/s: |
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Item Type: | Article |
Título de Revista/Publicación: | Thin Solid Films |
Date: | March 2013 |
ISSN: | 0040-6090 |
Volume: | 531 |
Subjects: | |
Freetext Keywords: | Copper nitride; Electronic structure; Sebeeck coefficient; Density functional theory |
Faculty: | E.T.S.I. Industriales (UPM) |
Department: | Ingeniería Nuclear [hasta 2014] |
Creative Commons Licenses: | Recognition - No derivative works - Non commercial |
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he nitrogen content dependence of the electronic properties for copper nitride thin films with an atomic percentage of nitrogen ranging from 26 ± 2 to 33 ± 2 have been studied by means of optical (spectroscopic ellipsometry), thermoelectric (Seebeck), and electrical resistivity measurements. The optical spectra are consistent with direct optical transitions corresponding to the stoichiometric semiconductor Cu3N plus a free-carrier contribution, essentially independent of temperature, which can be tuned in accordance with the N-excess. Deviation of the N content from stoichiometry drives to significant decreases from − 5 to − 50 μV/K in the Seebeck coefficient and to large enhancements, from 10− 3 up to 10 Ω cm, in the electrical resistivity. Band structure and density of states calculations have been carried out on the basis of the density functional theory to account for the experimental results.
Item ID: | 25689 |
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DC Identifier: | https://oa.upm.es/25689/ |
OAI Identifier: | oai:oa.upm.es:25689 |
DOI: | 10.1016/j.tsf.2013.01.030 |
Official URL: | http://www.sciencedirect.com/science/article/pii/S... |
Deposited by: | Memoria Investigacion |
Deposited on: | 05 May 2014 17:59 |
Last Modified: | 01 Apr 2015 22:56 |