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La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation
Citation
Bolonio Martín, David 
ORCID: https://orcid.org/0000-0002-9166-1861, Sánchez Palencia, Yolanda, García Martínez, María Jesús ORCID: https://orcid.org/0000-0001-7387-1788, Ortega Romero, Marcelo Fabián ORCID: https://orcid.org/0000-0002-8595-3884, Ortiz Menéndez, José Eugenio ORCID: https://orcid.org/0000-0002-5699-2593, Costafreda Mustelier, Jorge Luis ORCID: https://orcid.org/0000-0002-5125-4575 and Canoira López, Laureano
(2021).
La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation.
"Applied Petrochemical Research"
(n. 11);
pp. 353-362.
https://doi.org/10.1007/s13203-021-00283-x.
Description
| Title: | La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation |
|---|---|
| Author/s: |
|
| Item Type: | Article |
| Título de Revista/Publicación: | Applied Petrochemical Research |
| Date: | 28 September 2021 |
| Subjects: | |
| Faculty: | E.T.S.I. de Minas y Energía (UPM) |
| Department: | Ingeniería Geológica y Minera |
| Creative Commons Licenses: | None |
Abstract
The sodium form of Faujasite Y (Na-FAU) zeolite has been synthesized by the hydrothermal method, and it has been exchanged with ammonium sulphate and later with lanthanum (III) chloride solutions to obtain the La-FAU catalyst. The three zeolites Na-FAU, NH4+-FAU and La-FAU have been characterized by microcrystalline X-ray diffraction, X-ray fluorescence, surface area, pore volume and Brönsted acid sites. The La-FAU catalyst has been successfully activated with boron trifluoride etherate, and it has been tested in the alkylation reaction of isobutane with isobutene up to 112 h of time on stream, since the raw La-FAU catalyst showed a rapid deactivation.
Funding Projects
Type
Code
Acronym
Leader
Title
Horizon 2020
18259
Unspecified
Unspecified
BioLeach: Innovative Biotreatment of Raw Materials
More information
| Item ID: | 69433 |
|---|---|
| DC Identifier: | https://oa.upm.es/69433/ |
| OAI Identifier: | oai:oa.upm.es:69433 |
| DOI: | 10.1007/s13203-021-00283-x |
| Official URL: | https://link.springer.com/article/10.1007%2Fs13203... |
| Deposited by: | Dr. Jorge Luis Costafreda Mustelier |
| Deposited on: | 13 Jan 2022 07:17 |
| Last Modified: | 13 Jan 2022 07:17 |
