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La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation
Citation
Bolonio Martín, David and Sánchez Palencia, Yolanda and García Martínez, María Jesús and Ortega Romero, Marcelo Fabián and Ortiz Menéndez, José Eugenio and Costafreda Mustelier, Jorge Luis and Canoira López, Laureano (2021). La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation. "Applied Petrochemical Research" (n. 11); pp. 353-362. https://doi.org/10.1007/s13203-021-00283-x.
Description
| Title: | La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation |
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| Author/s: |
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| Item Type: | Article |
| Título de Revista/Publicación: | Applied Petrochemical Research |
| Date: | 28 September 2021 |
| Subjects: | |
| Faculty: | E.T.S.I. de Minas y Energía (UPM) |
| Department: | Ingeniería Geológica y Minera |
| Creative Commons Licenses: | None |
Abstract
The sodium form of Faujasite Y (Na-FAU) zeolite has been synthesized by the hydrothermal method, and it has been exchanged with ammonium sulphate and later with lanthanum (III) chloride solutions to obtain the La-FAU catalyst. The three zeolites Na-FAU, NH4+-FAU and La-FAU have been characterized by microcrystalline X-ray diffraction, X-ray fluorescence, surface area, pore volume and Brönsted acid sites. The La-FAU catalyst has been successfully activated with boron trifluoride etherate, and it has been tested in the alkylation reaction of isobutane with isobutene up to 112 h of time on stream, since the raw La-FAU catalyst showed a rapid deactivation.
Funding Projects
| Type | Code | Acronym | Leader | Title |
|---|---|---|---|---|
| Horizon 2020 | 18259 | Unspecified | Unspecified | BioLeach: Innovative Biotreatment of Raw Materials |
More information
| Item ID: | 69433 |
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| DC Identifier: | https://oa.upm.es/69433/ |
| OAI Identifier: | oai:oa.upm.es:69433 |
| DOI: | 10.1007/s13203-021-00283-x |
| Official URL: | https://link.springer.com/article/10.1007%2Fs13203-021-00283-x#Ack1 |
| Deposited by: | Dr. Jorge Luis Costafreda Mustelier |
| Deposited on: | 13 Jan 2022 07:17 |
| Last Modified: | 13 Jan 2022 07:17 |
