La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation

Bolonio Martín, David and Sánchez Palencia, Yolanda and García Martínez, María Jesús and Ortega Romero, Marcelo Fabián and Ortiz Menéndez, José Eugenio and Costafreda Mustelier, Jorge Luis and Canoira López, Laureano (2021). La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation. "Applied Petrochemical Research" (n. 11); pp. 353-362. https://doi.org/10.1007/s13203-021-00283-x.

Description

Title: La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation
Author/s:
  • Bolonio Martín, David
  • Sánchez Palencia, Yolanda
  • García Martínez, María Jesús
  • Ortega Romero, Marcelo Fabián
  • Ortiz Menéndez, José Eugenio
  • Costafreda Mustelier, Jorge Luis
  • Canoira López, Laureano
Item Type: Article
Título de Revista/Publicación: Applied Petrochemical Research
Date: 28 September 2021
Subjects:
Faculty: E.T.S.I. de Minas y Energía (UPM)
Department: Ingeniería Geológica y Minera
Creative Commons Licenses: None

Full text

[img]
Preview
PDF - Requires a PDF viewer, such as GSview, Xpdf or Adobe Acrobat Reader
Download (1MB) | Preview

Abstract

The sodium form of Faujasite Y (Na-FAU) zeolite has been synthesized by the hydrothermal method, and it has been exchanged with ammonium sulphate and later with lanthanum (III) chloride solutions to obtain the La-FAU catalyst. The three zeolites Na-FAU, NH4+-FAU and La-FAU have been characterized by microcrystalline X-ray diffraction, X-ray fluorescence, surface area, pore volume and Brönsted acid sites. The La-FAU catalyst has been successfully activated with boron trifluoride etherate, and it has been tested in the alkylation reaction of isobutane with isobutene up to 112 h of time on stream, since the raw La-FAU catalyst showed a rapid deactivation.

Funding Projects

TypeCodeAcronymLeaderTitle
Horizon 202018259UnspecifiedUnspecifiedBioLeach: Innovative Biotreatment of Raw Materials

More information

Item ID: 69433
DC Identifier: https://oa.upm.es/69433/
OAI Identifier: oai:oa.upm.es:69433
DOI: 10.1007/s13203-021-00283-x
Official URL: https://link.springer.com/article/10.1007%2Fs13203-021-00283-x#Ack1
Deposited by: Dr. Jorge Luis Costafreda Mustelier
Deposited on: 13 Jan 2022 07:17
Last Modified: 13 Jan 2022 07:17
  • Logo InvestigaM (UPM)
  • Logo GEOUP4
  • Logo Open Access
  • Open Access
  • Logo Sherpa/Romeo
    Check whether the anglo-saxon journal in which you have published an article allows you to also publish it under open access.
  • Logo Dulcinea
    Check whether the spanish journal in which you have published an article allows you to also publish it under open access.
  • Logo de Recolecta
  • Logo del Observatorio I+D+i UPM
  • Logo de OpenCourseWare UPM