Characterization cement pastes degraded in lanoratory solutions and physiochemical parameters employed for modeling the process

Antón Fuentes, Rebeca and Moragues Terrades, Amparo and Sanchez Espinosa, Elvira (2011). Characterization cement pastes degraded in lanoratory solutions and physiochemical parameters employed for modeling the process. In: "13th International Congress on the Chemistry of Cement", 03/07/2011 - 08/07/2011, Madrid, España.

Description

Title: Characterization cement pastes degraded in lanoratory solutions and physiochemical parameters employed for modeling the process
Author/s:
  • Antón Fuentes, Rebeca
  • Moragues Terrades, Amparo
  • Sanchez Espinosa, Elvira
Item Type: Presentation at Congress or Conference (Article)
Event Title: 13th International Congress on the Chemistry of Cement
Event Dates: 03/07/2011 - 08/07/2011
Event Location: Madrid, España
Title of Book: Proceedings of 13th International Congress on the Chemistry of Cement
Date: 2011
Subjects:
Faculty: E.T.S.I. Caminos, Canales y Puertos (UPM)
Department: Ingeniería Civil: Construcción
Creative Commons Licenses: Recognition - No derivative works - Non commercial

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Abstract

Previously degradation studies carried out, over a number of different mortars by the research team, have shown that observed degradation does not exclusively depend on the solution equilibrium pH, nor the aggressive anions relative solubility. In our tests no reason was found that could allow us to explain, why same solubility anions with a lower pH are less aggressive than others. The aim of this paper is to study cement pastes behavior in aggressive environments. As observed in previous research, this cement pastes behaviors are not easily explained only taking into account only usual parameters, pH, solubility etc. Consequently the paper is about studying if solution physicochemical characteristics are more important in certain environments than specific pH values. The paper tries to obtain a degradation model, which starting from solution physicochemical parameters allows us to interpret the different behaviors shown by different composition cements. To that end, the rates of degradation of the solid phases were computed for each considered environment. Three cement have been studied: CEM I 42.5R/SR, CEM II/A-V 42.5R and CEM IV/B-(P-V) 32.5 N. The pastes have been exposed to five environments: sodium acetate/acetic acid 0.35 M, sodium sulfate solution 0.17 M, a solution representing natural water, saturated calcium hydroxide solution and laboratory environment. The attack mechanism was meant to be unidirectional, in order to achieve so; all sides of cylinders were sealed except from the attacked surface. The cylinders were taking out of the exposition environments after 2, 4, 7, 14, 30, 58 and 90 days. Both aggressive solution variations in solid phases and in different depths have been characterized. To each age and depth the calcium, magnesium and iron contents have been analyzed. Hydrated phases evolution studied, using thermal analysis, and crystalline compound changes, using X ray diffraction have been also analyzed. Sodium sulphate and water solutions stabilize an outer pH near to 8 in short time, however the stability of the most pH dependent phases is not the same. Although having similar pH and existing the possibility of forming a plaster layer near to the calcium leaching surface, this stability is greater than other sulphate solutions. Stability variations of solids formed by inverse diffusion, determine the rate of degradation.

More information

Item ID: 12555
DC Identifier: http://oa.upm.es/12555/
OAI Identifier: oai:oa.upm.es:12555
Deposited by: Memoria Investigacion
Deposited on: 07 Aug 2012 08:13
Last Modified: 21 Apr 2016 11:49
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