Opportunities and challenges in the use of inorganic fullerene-like nanoparticles to produce advanced polymer nanocomposites

Naffakh Cherradi Hadi, Mohammed and Díez-Pascual, Ana M. and Marco, Carlos and Ellis, Garry and Gomez-Fatou, Marián A. (2013). Opportunities and challenges in the use of inorganic fullerene-like nanoparticles to produce advanced polymer nanocomposites. "Progress in Polymer Science", v. 38 (n. 8); pp. 1163-1231. ISSN 0079-6700. https://doi.org/10.1016/j.progpolymsci.2013.04.001.

Description

Title: Opportunities and challenges in the use of inorganic fullerene-like nanoparticles to produce advanced polymer nanocomposites
Author/s:
  • Naffakh Cherradi Hadi, Mohammed
  • Díez-Pascual, Ana M.
  • Marco, Carlos
  • Ellis, Garry
  • Gomez-Fatou, Marián A.
Item Type: Article
Título de Revista/Publicación: Progress in Polymer Science
Date: 1 August 2013
ISSN: 0079-6700
Volume: 38
Subjects:
Freetext Keywords: Inorganic fullerene-like (IF) nanoparticles; Polymer nanocomposites; Thermal, mechanical and tribological properties
Faculty: E.T.S.I. Industriales (UPM)
Department: Ingeniería y Ciencia de los Materiales [hasta 2014]
Creative Commons Licenses: Recognition - No derivative works - Non commercial

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Abstract

Polymer/inorganic nanoparticle nanocomposites have garnered considerable academic and industrial interest over recent decades in the development of advanced materials for a wide range of applications. In this respect, the dispersion of so-called inorganic fullerene-like (IF) nanoparticles, e.g., tungsten disulfide (IF-WS2) or molybdenum disulfide (IF-MoS2), into polymeric matrices is emerging as a new strategy. The surprising properties of these layered metal dichalcogenides such as high impact resistance and superior tribological behavior, attributed to their nanoscale size and hollow quasi-spherical shape, open up a wide variety of opportunities for applications of these inorganic compounds. The present work presents a detailed overview on research in the area of IF-based polymer nanocomposites, with special emphasis on the use of IF-WS2 nanoparticles as environmentally friendly reinforcing fillers. The incorporation of IF particles has been shown to be efficient for improving thermal, mechanical and tribological properties of various thermoplastic polymers, such as polypropylene, nylon-6, poly(phenylene sulfide), poly(ether ether ketone), where nanocomposites were fabricated by simple melt-processing routes without the need for modifiers or surfactants. This new family of nanocomposites exhibits similar or enhanced performance when compared with nanocomposites that incorporate carbon nanotubes, carbon nanofibers or nanoclays, but are substantially more cost-effective, efficient and environmentally satisfactory. Most recently, innovative approaches have been described that exploit synergistic effects to produce new materials with enhanced properties, including the combined use of micro- and nanoparticles such as IF-WS2/nucleating agent or IF-WS2/carbon fiber, as well as dual nanoparticle systems such as SWCNT/IF-WS2 where each nanoparticle has different characteristics. The structure–property relationships of these nanocomposites are discussed and potential applications proposed ranging from medicine to the aerospace, automotive and electronics industries.

More information

Item ID: 29333
DC Identifier: http://oa.upm.es/29333/
OAI Identifier: oai:oa.upm.es:29333
DOI: 10.1016/j.progpolymsci.2013.04.001
Official URL: http://www.sciencedirect.com/science/article/pii/S007967001300035X
Deposited by: Memoria Investigacion
Deposited on: 19 Jan 2015 16:38
Last Modified: 01 Oct 2015 22:56
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